A stability result for mountain pass type solutions of by Magrone P., Servadei R. PDF

By Magrone P., Servadei R.

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Extra resources for A stability result for mountain pass type solutions of semilinear elliptic variational inequalities

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That means a much slower increase of trx for larger ions (scaling as m1=3). 10, trx is independent* of z and, for near-spherical ions, scales as $m1=3. 1). 1). 15, we obtain 2m P0 T K0 P T0 ze   m P0 T 2 2 l ¼ Qtrx =2 ¼ E K0 P T0 ze trx ¼ (1:16) (1:17) * The derivation in Ref. 117] that found trx to depend on z has ignored the proportionality of K to z for a constant V and hence is incorrect. 4 Schematic plots showing how the same ion dynamics may appear to represent IMS (a) or MS (b) regimes, depending on the experimental timescale that in (a) is 10 times that in (b).

11. 9, and defining U, the voltage across the drift distance (the drift voltage), Revercomb and Mason22 obtained 1 p 1p R ¼ E zeKt=(kB T ln 2) ¼ zeU=(kB T ln 2) 4 4 (1:23) Hence the resolving power of conventional IMS depends only on the drift voltage, gas temperature, and ion charge state, but no other ion property such as mobility or Introduction into Separations Using Gas-Phase Transport 15 mass. Constraints of commercial power supplies and insulators have limited U in known IMS systems to <14 kV, which at room temperature means R < $220 for singly charged cations or anions.

Such uniform scaling was also observed55 for peptide ions in He, N2, Ar, and CH4, as one would expect considering that m > 500 Da, M < 40 Da, and m ) M hold for all four gases. 23 contains neither K nor M. , not in the Rayleigh limit), m depends on m and a change of M multiplies K of nonisobaric ions by different factors, which could materially affect the separation. 1 The interplay of those dependences is complex, but qualitatively many trends are understood. 11 2D IMS=MS spectra of (1þ) tryptic peptide ions from rabbit muscle aldolase generated using matrix assisted laser desorption ionization (MALDI).

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A stability result for mountain pass type solutions of semilinear elliptic variational inequalities by Magrone P., Servadei R.

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